9. Brad Pitt and Angelina Jolie
The third time was the charm for Angelina Jolie when she tied the knot with Brad Pitt on August 23, 2014 in France. They famously said that when they got married, it would be because everyone all over the world, gay or straight, would be allowed marriage equality. If you’ve seen their movie “Mr. & Mrs. Smith”, then you know they’ve got the chemistry!